Research Article 2026-04-22 posted v1

Visible-light-driven degradation of tetracycline hydrochloride over 15 wt% Cu-doped CeO2 photocatalyst: Mechanism and performance study

C
Chengcheng Li Independent Researcher

Abstract

In this study, a series of Cu nanoparticle-loaded CeO₂ (Cu-CeO₂) photocatalysts were successfully prepared through a hydrothermal route. The products were applied in the photocatalytic degradation of tetracycline hydrochloride (TCH) under visible light irradiation. The results showed that the 15 wt% Cu-CeO₂ sample achieved the best activity, degrading 85.3% of TCH within 60 min. The apparent reaction rate constant reached 33.84×10⁻³ min⁻¹, which was 5.12 times higher than that of pure CeO₂. The improved performance is mainly attributed to the narrowed bandgap, enhanced visible-light absorption, and accelerated charge separation efficiency induced by Cu loading. Based on characterization results and quenching experiments, a reasonable photocatalytic mechanism for TCH degradation over Cu-CeO₂ was proposed.

Citation Information

@article{chengchengli2026,
  title={Visible-light-driven degradation of tetracycline hydrochloride over 15 wt% Cu-doped CeO2 photocatalyst: Mechanism and performance study},
  author={Chengcheng Li},
  journal={Research Square},
  year={2026},
  doi={https://doi.org/10.21203/rs.3.rs-9477633/v1}
}
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